Oxidation of Hantzsch 1,4- Dihydropyridines to Pyridines with Thallium Triacetate
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Abstract:
Hantzsch 1, 4-dihydropyridines (1,4-DHPs) can be oxidized to the corresponding pyridine derivatives by thallium triacetate in high yields.
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oxidation of hantzsch 1,4- dihydropyridines to pyridines with thallium triacetate
hantzsch 1, 4-dihydropyridines (1,4-dhps) can be oxidized to the corresponding pyridine derivatives by thallium triacetate in high yields.
full textAROMATIZATION OF HANTZSCH 1,4- DIHYDROPYRIDINES WITH ZINC CHLOROCHROMATE NONAHYDRATE
Hantzsch 1 ,4- dihy&opyridines are rapidly oxidized to the corresponding pyridine derivatives using zinc chlorochromate nonahydrate [Zn(C1CrO ) .9H O] in dichloromethane at room temperature. In addition to aromatization, no loss of the 4- substituent is observed
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An eco-friendly "on-water" protocol for efficient catalyst-free synthesis of the Hantzsch dihydropyridines from aryl, heteroaryl, alkyl, and vinylogous aldehydes has been developed with minimum auxiliary substances, toxic reagents, organic solvents, and disposal problems.
full textSodium Hypochlorite-Dowex 1X8-200: A Convenient Oxidizing Reagant
The polymer supported hypochlorite ion is a facile selective oxidizing agent for the oxidation of various alcohols to aldehydes and ketones. Similarly is successfully oxidizes various Hantzsch type 1,4- dihydropyridines to corresponding pyridines.
full textaromatization of hantzsch 1,4- dihydropyridines with zinc chlorochromate nonahydrate
hantzsch 1 ,4- dihy&opyridines; are rapidly oxidized to the corresponding pyridine derivatives using zinc chlorochromate nonahydrate [zn(c1cro ) .9h o] in dichloromethane at room temperature. in addition to aromatization, no loss of the 4- substituent is observed
full textN,N'-ethylene-bis(benzoylacetoniminato) copper (II), Cu(C22H22N2O2), a new reagent for aromatization of Hantzsch 1,4-dihydropyridines.
A variety of Hantzsch 1,4-dihydropyridines were oxidized to their corresponding pyridines in high yields in the presence of Cu(C22H22N2O2) in refluxing acetic acid.
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Journal title
volume 22 issue 2
pages 9- 11
publication date 2003-12-01
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